Beilstein J. Nanotechnol.2019,10, 1994–2003, doi:10.3762/bjnano.10.196
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Keywords: antifog; antifouling; biomimetic coatings; metal–organic frameworks (MOFs); superhydrophilic; superoleophobic; thin films; vapor-assistedconversion; Introduction
Over millions of years, plants and animals have evolved a spectrum of surface designs enabling specific wetting properties tailored
the solid/water interface on the identical pelletized sample.
A) A scheme of the vapor-assistedconversion (VAC) set up and the resulting nanostructured films. B) SEM top view, 30° tilted cross-section and the related GIWAXS pattern of the Co-CAT-1 film. C) SEM top view, 30° tilted cross-section
were synthesized as highly crystalline bulk materials. The M-CAT-1 surface energy was estimated by contact angle measurements using pellet samples exposing nonoriented crystallites on the surface. Next, oriented and compact Co- and Ni-CAT-1 films were deposited on gold surfaces by vapor-assisted
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Figure 1:
A) Synthesis scheme of M-CAT-1 using 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and the respectiv...